Theoretical Study of Reaction Paths and Transition States on Conversion Methane into C2 Hydrocarbons Through Plasma
نویسندگان
چکیده
منابع مشابه
Catalytic and Non-catalytic Conversion of Methane to C2 Hydrocarbons in a Low Temperature Plasma
The direct conversion of methane to C2 hydrocarbons, in a quartz tube reactor enforced by a DC corona discharge, was investigated at atmospheric pressure. The process was carried out in the presence of metal oxide catalysts of Mn/W/SiO2, Mn/W/SiO2 (tetraethyl orthosilicate, TEOS), and Mn/W/CNT (supported on carbon nanotubes). The total yield to C2 hydrocarbons in the presence of metal oxide cat...
متن کاملcatalytic and non-catalytic conversion of methane to c2 hydrocarbons in a low temperature plasma
the direct conversion of methane to c2 hydrocarbons, in a quartz tube reactor enforced by a dc corona discharge, was investigated at atmospheric pressure. the process was carried out in the presence of metal oxide catalysts of mn/w/sio2, mn/w/sio2 (tetraethyl orthosilicate, teos), and mn/w/cnt (supported on carbon nanotubes). the total yield to c2 hydrocarbons in the presence of metal oxide cat...
متن کاملSynergetic Effects of Plasma, Temperature and Diluant on Nonoxidative Conversion of Methane to C2+ Hydrocarbons in a Dielectric Barrier Discharge Reactor
Noncatalytic and nonoxidative conversion of methane in a dielectric barrier discharge (DBD) reactor is examined at different temperatures, gas residence times and input powers. In addition, the ratio of methane to helium as a diluant, is changed in the range of 0.6 to 1.8. Results show significant synergetic effects of plasma, temperature and helium on the methane conversion and C2+</s...
متن کاملEnzyme homologues have distinct reaction paths through their transition states.
Recent studies of the bacterial enzymes EcMTAN and VcMTAN showed that they have different binding affinities for the same transition state analogue. This was surprising given the similarity of their active sites. We performed transition path sampling simulations of both enzymes to reveal the atomic details of the catalytic chemical step, which may be the key for explaining the inhibitor affinit...
متن کاملsynergetic effects of plasma, temperature and diluant on nonoxidative conversion of methane to c2+ hydrocarbons in a dielectric barrier discharge reactor
noncatalytic and nonoxidative conversion of methane in a dielectric barrier discharge (dbd) reactor is examined at different temperatures, gas residence times and input powers. in addition, the ratio of methane to helium as a diluant, is changed in the range of 0.6 to 1.8. results show significant synergetic effects of plasma, temperature and helium on the methane conversion and c2+ selectiviti...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chinese Journal of Chemical Engineering
سال: 2007
ISSN: 1004-9541
DOI: 10.1016/s1004-9541(07)60032-9